CAS Search
Related Chemical Product
Buy Chemical NO: 120-51-4
  • Urgent Purchase CAS NO.:120-51-4
  • Please post your buying leads! Our suppliers will contact you later!
  • For suppliers to better understand your request, enter more info here.

* Product Name:
CAS No.:
* Quantity:
 
 Metric Ton     Kilogram    Gram    Pound
* Valid For:
 5 Days    15    1 Month    3 Month    6 Month    1 Year
* Description:

Max 2000 characters.  Please enter detailed description for the product.
* Email:
 

Benzyl benzoate ( CASNO:120-51-4 )

Identification and Related Records
Name:
Benzyl benzoate
CAS Registry number:
120-51-4
Iupac name:
benzyl benzoate
Synonyms:
Benzoic acid benzyl ester
Ascabin
Ascabiol
Benylate
Benzyl alcohol benzoic ester
BENZOATO DE BENCILO
Benzoic acid phenylmethyl ester
Benzyl benzene carboxylate
Benzyl phenylformate
Phenylmethyl benzoate
Scabagen
Vanzoate
EINECS(EC#):
204-402-9
Molecular Formula:
C14H12O2
Molecular Weight:
212.25
Inchi:
InChI=1/C14H12O2/c15-14(13-9-5-2-6-10-13)16-11-12-7-3-1-4-8-12/h1-10H,11H2
InChIKey:
SESFRYSPDFLNCH-UHFFFAOYSA-N
Canonical SMILES:
C1=CC=C(C=C1)COC(=O)C2=CC=CC=C2
Chemical and Physical Properties
Appearance:
colourless oily liquid with pleasant aromatic odor
Density:
1.118
Melting Point:
18-20℃
Boiling Point:
323℃
Vapour:
0.00025mmHg at 25°C
Refractive Index:
1.567-1.57
Flash Point:
147℃
Water:
practically insoluble
Solubilities:
Insoluble
Color/Form:
LEAFLETS OR OILY LIQ
CLEAR, COLORLESS LIQ
Stability:
Stable. Substances to be avoided include strong oxidizing agents. Combustible.
HS Code:
29163100
Storage temp:
Store in a cool, dry place. Keep container closed when not in use. Keep from contact with oxidizing materials.
Spectral properties:
INDEX OF REFRACTION: 1.5681 AT 21 DEG C/D
MAX ABSORPTION (ALCOHOL): 229 NM (LOG E= 4.2), 267 NM (LOG E= 3.0), 272 NM (LOG E= 3.0), 280 NM (LOG E= 2.9); SADTLER REFERENCE NUMBER: 1509 (IR, PRISM), 253 (IR, GRATING)
Intense mass spectral peaks: 105 m/z (100%), 91 m/z (42%), 77 m/z (28%), 51 m/z (12%)
IR: 6248 (Coblentz Society Spectral Collection)
UV: 427 (Sadtler Research Laboratories Spectral Collection)
NMR: 627 (Varian Associates NMR Spectra Catalogue)
MASS: 1511 (Atlas of Mass Spectral Data, John Wiley & Sons, New York)
Computed Properties:
Molecular Weight:212.24388 [g/mol]
Molecular Formula:C14H12O2
XLogP3:4
H-Bond Donor:0
H-Bond Acceptor:2
Rotatable Bond Count:4
Exact Mass:212.08373
MonoIsotopic Mass:212.08373
Topological Polar Surface Area:26.3
Heavy Atom Count:16
Formal Charge:0
Complexity:213
Isotope Atom Count:0
Defined Atom Stereocenter Count:0
Undefined Atom Stereocenter Count:0
Defined Bond Stereocenter Count:0
Undefined Bond Stereocenter Count:0
Covalently-Bonded Unit Count:1
Feature 3D Acceptor Count:1
Feature 3D Ring Count:2
Effective Rotor Count:4
Conformer Sampling RMSD:0.6
CID Conformer Count:21
Safety and Handling
Hazard Codes:
Xn:Harmful
Risk Statements:
R22
Safety Statements:
S25
Safety:
Hazard Codes:?HarmfulXn
Risk Statements: 22?
R22:Harmful if swallowed.
Safety Statements: 25?
S25:Avoid contact with eyes.
WGK Germany: 2
RTECS: DG4200000
HS Code: 29163100
PackingGroup:
Z01
Skin, Eye, and Respiratory Irritations:
Benzyl benzoate is relatively nontoxic but may irritate the skin and eyes.
Transport:
220kgs
Fire Fighting Procedures:
WATER, FOAM, CARBON DIOXIDE, WATER SPRAY OR MIST, DRY CHEM...
Fire Potential:
FIRE HAZARD SLIGHT WHEN EXPOSED TO HEAT OR FLAME
Formulations/Preparations:
USEPA/OPP Pesticide Code 009501; Trade Names: Benylate.
BENZYL BENZOATE, USP IS USED AS 25% LOTION (BENZYL BENZOATE LOTION, USP).
...AVAIL GENERICALLY /AS/ EMULSION 50% IN 16 & 64 OZ CONTAINERS; LOTION 27% IN 16 & 64 OZ CONTAINERS & 50% IN 4 & 16 OZ CONTAINERS.
MITONE (WT/WT) ACTIVE INGREDIENTS: BENZYL BENZOATE 20.0%, BENZOCAINE 2.0%, ROTENONE 0.3%; INERT INGREDIENTS: 77.7% (ISOPROPYL ALCOHOL 73.9%, OTHER 3.8%).
DEMSARDEX (WT/WT) ACTIVE INGREDIENTS: BENZYL BENZOATE 36.72%, LINDANE (GAMMA ISOMER OF BENZENE HEXACHLORIDE) 0.54%; INERT INGREDIENTS (ISOPROPYL ALCOHOL 62.74%).
BENZYL-HEX (WT/WT) ACTIVE INGREDIENTS: BENZYL BENZOATE 20.0%, ROTENONE CP 0.5%, GAMMA ISOMER OF BENZENE HEXACHLORIDE (FROM LINDANE) 0.25%, 2,2'-METHYLENEBIS (4-CHLOROPHENOL) 0.5%; INERT INGREDIENTS 78.75%.
MANGE-RID (WT/WT) ACTIVE INGREDIENTS: BENZYL BENZOATE 33.0%, SOAP (ANHYDR) 7.5%; INERT INGREDIENTS 59.5%.
Liquid containing 30% technical
Exposure Standards and Regulations:
Benzyl benzoate is an indirect food additive for use as a component of adhesives.
Reactivities and Incompatibilities:
Can react with oxidizing materials
Other Preventative Measures:
SRP: The scientific literature for the use of contact lenses in industry is conflicting. The benefit or detrimental effects of wearing contact lenses depend not only upon the substance, but also on factors including the form of the substance, characteristics and duration of the exposure, the uses of other eye protection equipment, and the hygiene of the lenses. However, there may be individual substances whose irritating or corrosive properties are such that the wearing of contact lenses would be harmful to the eye. In those specific cases, contact lenses should not be worn. In any event, the usual eye protection equipment should be worn even when contact lenses are in place.
SRP: Local exhaust ventilation should be applied wherever there is an incidence of point source emissions or dispersion of regulated contaminants in the work area. Ventilation control of the contaminant as close to its point of generation is both the most economical and safest method to minimize personnel exposure to airborne contaminants.
Protective Equipment and Clothing:
Benzyl benzoate is relatively nontoxic but may irritate the skin and eyes.
Specification:
?Benzyl benzoate , its cas register number is 120-51-4. It also can be called Benylate ; Benzoic acid, benzyl ester ; Benzoic acid, phenylmethyl ester ; Phenylmethyl benzoate ; Novoscabin ; Peruscabin ; Peruscabina ; Scabagen ; Scabanca ; Scabide ; Scabiozon ; Scabitox ; Scobenol ; Spasmodin .It is a?colourless oily liquid with pleasant aromatic odor.
Octanol/Water Partition Coefficient:
Log Kow = 3.97
Disposal Methods:
SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.
Use and Manufacturing
Use and Manufacturing:
Methods of Manufacturing

Produced from benzyl alcohol and sodium benzoate in the presence of triethylamine or transesterification of methyl benzoate with benzyl alcohol in the presence of an alkali benzyl oxide; in another manufacturing process benzaldehyde is condensed to form benzyl benzoate in the presence of sodium (Claisen-Tishchenko condensation)
U.S. Production

(1972) 1.85X10+8 GRAMS
(1975) 3.35X10+8 GRAMS
(1991) 287,000 kg
Usage:
Camphor substitute in celluloid & plastic pyroxylin compound, pediculicide, acaricide.
Biomedical Effects and Toxicity
Pharmacological Action:
- Pesticides designed to control insects that are harmful to man. The insects may be directly harmful, as those acting as disease vectors, or indirectly harmful, as destroyers of crops, food products, or textile fabrics.
Therapeutic Uses:
MEDICATION (VET): APPLIED IN TREATMENT OF SARCOPTIC & DEMODECTIC MANGE IN DOG.
Formulated in emulsions or lotions (200-350 g/l) it is used on humans as an acaricide (scabicide). For veterinary application, benzyl benzoate is used as a scabicide and pediculicide.
Former use: ... Benzyl benzoate was efficacious in the treatment of a number of conditions including excessive peristalsis of the intestine as in diarrhea and dysentery, intestinal colic and enterospasm, pylorospasm, spastic constipation in which there was a tonic spastic condition of the intestine, biliary colic, ureteral or renal colic, spasm of the urinary bladder, spasms associated with contraction of seminal vesicles, uterine colic as in spastic dysmenorrhea, arterial spasm including hypertension, and bronchial spasms as in asthma and pertussis. The use of benzyl benzoate in the treatment of these conditions has been superseded by the use of other more effective drugs.
Benzyl benzoate is a relatively harmless substance that in high concn is toxic to Acarus scabiei. The compound has been widely used in the treatment of scabies and is also useful in the treatment of pediculosis. Benzyl benzoate is used as a 26 to 30% lotion. In the treatment of scabies, the lotion is applied to the entire body from the neck down after thorough cleansing. When the first application is dry, a second coat is applied. The residue is washed off after 24 hours.
Biomedical Effects and Toxicity:
Benzoic acid is conjugated with glycine to yield benzoylglycine (hippuric acid) and with glucuronic acid to yield benzoylglucuronic acid. These conjugates are eliminated in the urine in varying ratios depending on species and dose. Herbivorous animals excrete benzoic acid almost entirely as hippuric acid, whereas carnivores and omnivores usually excrete moderate to high levels of the glucuronide.
The percutaneous absorption of benzyl benzoate measured in vivo in human and monkey studies. With the application sites occluded, 54% of the applied dose penetrated human skin in 24 hr compared with 69% absorption in the monkey skin. [Bronaugh RL et al; Food Chem Toxicol 28 (5): 369-74 (1990)] PubMed Abstract
Chemical Company
ZITONG INDUSTRY CO., LIMITED:
 
snbmIQZmMxgz:
 
Yancheng Ruibiao Pharmaceuticals and Chemicals Factory:
profile: Yancheng Ruibiao Pharmaceutical drugs and Chemicals Factory handles pharmaceutical raw material and chemical intermediates. Our product includes dextran 40,Iron Dextran Powder, mucochloric acidity, dl-mandelic acidity and N-Chlorosuccinimide. We offer bromosuccinimide, tetrahydrofurfuryl bromide, 2-amino-5-chloro benzophenone, 4-chloro-3-nitro benzoic acidity and 5-hydroxy isophthhalic acidity. 
Wuhan Hezhongyc Bio-Chemical Manufacture Co., Ltd:
 
东莞市天翊网络科技有限公司:
 
Wuxi Dongao Nonferrous Casting Co., Ltd.:
Wuxi Dongao Nonferrous Casting Co., Ltd. is a growing modernized production enterprise undertaking pressure-bearing sand castings products and processing after 30 years of development,Website:http://www.danon-ferrous.com, and has experienced casting experts and employees, who all-round embody the casting level and technical ability of our company and guarantee to provide customers with excellent products. The company mainly produces all kinds of pumps and high pressure valve products, such as shell, valve body, impeller, ring, gland and other complex copper castings, which materials are aluminum bronze, tin bronze C95800, C95500, C83600, C87600, RG5, RG9, RG10, etc. Such products are used in shipbuilding, machinery and other industries, and the company has the annual production capacity of 
Zhongbei Northland Bio-Chem Industry Co., Ltd.:
Thanks for visiting Zhongbei Northland Bio-Chem Industry Co., Ltd a worldwide chemical companies since 2002. We're focused on developing, manufacturing and marketing active components rich in bio-activity and safety, serving the dietary supplements and functional food ,cosmetic and pharmaceutical industries. Qualities: Honored using the title of No. 1 Strong Move Businesses by Heilongjiang Provencial Government. Warehouses located in the US; Strong sourcing capability of working with over 100 manufacturers in China;GMP standard training courses for natural pigment, traditional drug extracts, chemical-synthetic , Auxiliary workshops under 13000 square metres Quality assurance system;In-house and third party laboratories;R &lifier D laboratory with 27 technical persons.Production w 
Wenzhou Golden business engine:
 
Skylead Chemicals Limited:
 
Chengdu Zetian Chemical Co., Ltd.:
Chengdu Zetian Chemical Co., Ltd., Like a professional manufacturer, exporter in China, we always devote ourselves to R&D, creating and purchase on organic fertilizer, enhanced the standard chelating technology to create the merchandise to be more appropriate towards the market, which gained the broader acceptance and praise, our brand FZT accomplished victory-win with clients at home &lifier abroad, and meantime increased up in to the first make of EDDHA-Fe in China. EDDHA iron(Further ed) FertilizerEDDHSA iron(Further ed) Fertilizer  
中航一飞(天津)科技有限公司:
 
Wuyi Besse Electric Appliance Co., Ltd:
Wuyi Besse Electric Appliance Co. Ltd was founded in 2012,Website:http://www.zgbesse.com, Formerly is Wuyi Besse Electric Appliance Factory. We covers an area of more than 3200 square meters. It is an integrate development, production and sales of high-tech enterprise, specializing in the " zgbes" brand kitchen appliance and marketing. Our company has a number of experienced technician and excellent sales staff that can meet a variety of customer requirements, provide the appropriate products and practical advice. Now, our main products are household kitchen appliance, such as gas stove, gas cooker etc. Our production ability is over 1000000 PCS per year. The company with the quality first as the supreme principle. We strict to control of all aspects of spare parts and production. We have 
HANGZHOU HIDEA POWER MACHINERY CO.LTD:
Hangzhou Hidea Power Machinery Co.,Ltd. is a public company and professional manufacturer in the field of outboard motors. Hidea company owns advanced production line,Website:http://www.hideaboatmotor.com, strict inspection system for parts and finished products, a strong team of talents in R&D and management. Hidea company has been approved for many international certification, such as EPA from USA, CE from EU, VCA from England. With stable and reliable product quality and perfect after-sales service, Hidea has gained a good reputation. With the concept of people oriented, credibility and innovation, perfect service, Hidea concentrates on research and producing environmentally products, so as to contribute to a green world. Outboard motors and outboard machine accessories Water recreat 
Shenyang mkxy:
 
Henan Weikang Health Food Co.,Ltd:
profile: Henan Weikang health food Co.,Ltd is an expert in bee items, natural extracts & recycleables for that food, Cosmetics and pharmaceutical industries. Our bee items include propolis, Royal Jelly, pollen and Beeswax. Our plant oil includes garlic clove, Wheat Germ, flaxseed, Grape seed and rose oil. Our powder items include apple pectin, Apple, pumpkin, carrot and Garlic clove Powder. Our items are released to numerous foreign nations. In garlic clove oil, we provide natural garlic clove oil and Deodorized Garlic clove Oil. We stock refined wheat germ oil, Decolored wheat germ oil and Virginal wheat germ oil. 
Wuhan Grand Pharmaceutical Co., Ltd.:
 
Wuxi Flying International Trading Co., Ltd.:
 
Baiyun Chen DASHIQIAO plant ash:
 
Yixing Sunan Petrochemical Auxiliary Factory:
 
东莞市天翊网络科技有限公司: